Senin, 01 Oktober 2012

Uniqueness of Carbon Atoms

Has Ability Form Chain - One of the perks of carbon that is not owned by the other elements is their ability to form chains of carbon atoms, which we hereafter refer to as the carbon chain.

Carbon chains may be either a single bond, double bond, or a triple bond. Forms of carbon chains themselves are very varied, there is a straight (unbranched), there is a branching, there are open, and there is a closed (circular). Various forms of carbon chains presented in the figure below.


 

Compounds with an open chain compounds called aliphatic compounds while closed or circular chain called cyclic compounds. The compounds are all carbon bond is a single bond, - C - C - called unsaturated carbon compounds, while having a carbon-carbon double bond, - C - C -, or triple - C = C -, called unsaturated carbon compounds.

Cyclic compounds having conjugated bonds, the carbon-carbon bond alternating single and dual, are called aromatic compounds. All cyclic compounds that are not included aromatic compounds are called alicyclic compounds, (the word comes from the word ali alicyclic and cyclic). These compounds are called alicyclic compound because it has a circular shape, but its properties resemble aliphatic compounds.


 

Why carbon can form so many compounds, with very varied types? Why is this not happening in the adjacent element or elements are classified with the carbon in the periodic table? BC has the electron configuration of atoms 2 4. The four valence electrons distributed on the four C atoms in a symmetrical position.

  
The ability to bind carbon atoms and follow the octet rule is different from other atoms, even within a single class. For example, boron and nitrogen atoms. Electron configuration of two atoms is J3: 2 3 and _n: 2 5. Boron atom has three valence electrons so that when the covalent bonds, resulting compounds do not follow the octet Kaidan. Note the Lewis structure of the compound following BH3

 

The compound BH, has the form of a symmetrical molecule and has three covalent bonds. In contrast to compound BH3, NH3 compounds follow the octet rule, but the shape of the molecule is not symmetrical because there is a lone pair.

 
Thus, compounds BH, and NH3 only has three covalent bonds. What about silicon? The silicon atom has an electron configuration 2 8 4. The silicon atom has four valence electrons with the carbon atom. The four electrons in the silicon atom is distributed on four sides symmetrically.   

The carbon atom has four valence electrons with the atomic radii price the smallest of the atomic radius of other elements in the group IVA. It facilitates the C atom to form covalent bonds with other atoms, especially with atomic H, O, N, and halogen atoms (F, Cl, Br, and I). Covalent bonds are formed to meet the octet rule. The carbon atom can form up to four covalent bonds. Covalent bond formed by atoms C is more powerful than other covalent bonds, so that the carbon compounds are stable.

The position of carbon atoms in the periodic table in the middle so it has a moderate electronegativity value (2.5). This trait causes the carbon atoms can bind atoms having electronegativity greater or even smaller. The carbon atom can have a positive oxidation state (+2, +4), negative (-2, -4), or even zero.
 

ethylene gas


Ethylene is a growth hormone that is produced from normal metabolism in plants. Role of ethylene in fruit ripening and loss daun.Dalam fruit ripening, ethylene working to solve the chlorophyll in young fruit, so the fruit has only xantofil and carotene. Thus, the color becomes orange or red fruit

Ethylene is a growth hormone that is produced from normal metabolism in plants. Role of ethylene in fruit ripening and leaf loss. Ethylene is also called ethane. Additionally Ethylene (IUPAC name: ethene) is an organic compound, a hydrocarbon with the formula C2H 4 or H2C = CH2. It is a colorless flammable gas with a faint "sweet and musky smell" when pure. [3] It is the simplest alkene (hydrocarbons with carbon-carbon double bonds), and the simplest unsaturated hydrocarbons after acetylene (C2H 2).
Hormone Ethylene Gas is a gaseous hormone in plant life active in ripening fruit. Applications containing Ethephon, the synthetic Ethylene optimal performance so that goals can be achieved pieces cook faster. (eg: Etephon, Protephon) trademarks include: Prothephon 480SL. Ethylene gas is found in many old fruit.

As the influence of ethylene activity, namely:

 Temperature. High temperature (> 350C) ethylene formation does not occur. The optimum temperature of formation of ethylene (tomatoes, apples) 320C, while for the other fruits lower.

Mechanical wounding and infection. Fruit broken, bruised, and a nest of caterpillars eat

 radioactive rays

 Presence of O2 and CO2. When O2 is lowered and elevated CO2 inhibited the maturation process. And if the situation does not occur anaerobically ethylene formation

The interaction with the hormone auxin. If the concentration of auxin increases, ethylene will increase

 The level of maturity

PETROLEUM


PETROLEUM


1 Oil of Inorganic Materials

Stated by Berthelot. He said the metal - alkali metals react with CO2 in the earth at high temperatures to form acetylene gas (C2H2), which later formed the other hydrocarbon compounds.

Another hypothesis by Dmitri Mendeleev Ivaovick, iron carbide in the Earth react with water and produce acetylene gas. This reaction is similar to the reaction that occurs between a rock carbide and water.

2 Crude Oil from Organic Matter

This theory stated by o.g. Macquir, based on the source of coal which is also derived from plants - plants.

As for the theory that oil comes from animals, first proposed by JPLesley. Then another scientist named B. Haquet petroleum distillation experiment of mollusks. Another experiment conducted by H. Hofer and C.Eugler. They do a distillation of the clam meat and fish at a temperature of 3000C - 4000C and a pressure of 10 atm. In substance produced substances resembling petroleum.

Based on the theory of creation, the oil derived from the weathering of living organisms that lasts very long (millions - millions of years). Petroleum formation requires an environment that can provide high levels of organic matter and allow preservation so that no oxidation or spoilage. The beach area has a river estuary facing the open sea, are more likely to produce organic matter. Furthermore, the organic matter is spread into a smooth slab of shale rock, accumulated and concentrated. Furthermore, it moved into the rocks and trapped in sedimentary rocks.

OIL COMPONENTS
1 Straight Chain Aliphatic Hydrocarbon Compounds

Also called normal alkanes or paraffin. These compounds are widely available in natural gas and oil, which has a short carbon chain

2 Forms of Cyclic Hydrocarbons Compounds

Cyclic hydrocarbons are hydrocarbons or cycloparaffins cycloalkane group. Hydrocarbon compounds have the same molecular formula alkenes, but has no double bond and form a ring structure. In general, cyclic hydrocarbons in petroleum a mixture of cyclopentane and cyclohexane called naften. In petroleum, the intermolecular cyclic sometimes - sometimes combine to form a molecule that consists of several cyclic compounds.

3 Compounds Aliphatic Hydrocarbon Chain Branching

Example: isoalkana or isoparaffins

Amount of hydrocarbons is not as straight-chain aliphatic hydrocarbons and cyclic hydrocarbons form.

4 Compound Aromatic Hydrocarbons

Is a cyclic hydrocarbon compounds that form hexagons, doubly bonded hose - alternating, and unsaturated hydrocarbons. Amount of hydrocarbons is at least among the other types. In general, these aromatic hydrocarbons found in petroleum that has a large number of C atoms






Crude oil (crude oil) is mostly composed of compounds of saturated hydrocarbons (alkanes). The unsaturated hydrocarbons (alkenes, alkynes and alkadiena) very little dkandung by oil, because susceptible addition to alkanes.

Because petroleum berasl of fossil organisms, mak oil containing sulfur compounds (0.1 to 7%), nitrogen (0.01 to 0.9%), oxygen (0.6-0.4%) and metal compounds in amounts smaller sanagt. Crude oil is separated into a number of fractions through a distillation process (distillation).

Separation of crude oil into the pure components (single compound) is not possible and also not prakstis because too many compounds present in the oil and hydrocarbons have isomers with close boiling points. Fractions obtained from the distillation of crude oil is a mixture of hydrocarbons that boil at a certain temperature trajectory. For example, the fraction of kerosene (kerosene) is composed of a mixture of compounds boiling between 180 0 C-250 0 C. Distillation process is done by using a distillation column or tower.

Senin, 24 September 2012

chemistry hydrocarbon

In chemistry, a hydrocarbon is a compound composed of the elements carbon (C) and hydrogen atoms (H). The entire chain hydrocarbons having carbon and hydrogen atoms bonded to the chain. The term is used also as a sense of aliphatic hydrocarbons.

For example, methane (swamp gas) is a hydrocarbon with one carbon atom and four hydrogen atoms: CH4. Ethane is a hydrocarbon (more specifically, an alkane) consisting of two carbon atoms are united by a single bond, each of which binds to three carbon atoms: C2H6. Propane has three C atoms (C3H8) and beyond (CnH2 · n +2)



what do you think ?????





Hydrocarbons Compounds



Hydrocarbons are the most simple carbon compounds. From the name, hydrocarbon compounds are compounds composed of only carbon and hydrogen atoms karbon.Berdasarkan atomic arrangement of carbon atoms in the molecule, carbon compounds are divided into two major categories, namely aliphatic compounds and cyclic compounds.

   1.  Aliphatic hydrocarbons

Aliphatic hydrocarbons are carbon compounds chain opens its C and C it allows branched chain. Based on the amount of the bond, aliphatic hydrocarbons, aliphatic compounds are divided into saturated and unsaturated.

a. The compound is a saturated aliphatic C chain aliphatic compounds it contains only single bonds only. This group is called alkanes.


b. Unsaturated aliphatic compounds are aliphatic compounds, varying chain C double bond or triple. If you have duplicate named alkenes and alkynes have triple called.
 

 2.Cyclic hydrocarbons

Cyclic hydrocarbon compound is a compound of carbon chain C and its circular hoop may also bind the side chain. This group divided into alicyclic and aromatic compounds.

  a. alicyclic compounds are carbon compounds that make up the chain aliphatic alicyclic compounds tertutup


b. Aromatic compounds are compounds composed of 6 carbon atoms that form a chain C benzene.